Analytical chemistry council

METHODS AND OBJECTS OF CHEMICAL ANALYSIS

 

An international journal devoted to all aspects of analytical chemistry

ISSN 2413-6166 (Online), ISSN 1991-0290 (Print)

Kiev University
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Determination of the Geographical Origins of Olive Mill Wastewater: FTMIR Spectroscopy and Chemometric Algorithms for Accurate Classification

Faiçal Sbai El Otmani†; Aimen El Orche†‡; Mouad Mouhsin†; Meriem Kasbaji†; Ayoub Ait Oumghar†; Mohamed Mbarki† and Mustapha Oubenali†*

† Team of Analytical & Computational Chemistry, Nanotechnology and Environment, Faculty of Science and Technologies, Sultan Moulay Slimane University, BP 523, Beni Mellal, Morocco;
‡ Laboratory of drug sciences, biomedical research, and biotechnology, Faculty of Medicine and Pharmacy, Hassan II University of Casablanca, Morocco

* Corresponding authors

*e-mail: mustapha.oubenali@gmail.com

Methods Objects Chem. Anal., 2024, 19(4), p. 206-212

https://doi.org/10.17721/moca.2024.206-212

The article is distributed under open access Creative Commons Attribution License CC BY 4.0.

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Abstract

The present research studies the geographical classification of olive mill wastewater (OMWW) samples using FT-MIR spectroscopy and chemometric recognition algorithms. The study focuses on samples collected from two regions in Morocco: BeniMellal-Khenifra and Fes-Meknes. Principal Component Analysis (PCA) has been applied to the spectral data, revealing distinct clustering of OMWW samples based on their geographical origin. Additionally, Partial Least Squares Discriminant Analysis (PLS-DA) has been employed to develop a classification model for accurate sample categorization. The PLS-DA model presented high sensitivity and specificity, achieving perfect classification rates during the calibration phase. Validation results show the model's capability to accurately identify the majority of samples, with a minor misclassification. These results confirm the potential of FTMIR spectroscopy and chemometric recognition algorithms for authentication, and traceability in the olive oil industry. Further research can explore the extension of this methodology to other regions and agricultural by-products, incorporating advanced machine learning algorithms for enhanced classification accuracy. Overall, the present study contributes to enhance environmental waste management research by addressing OMWW disposal concerns and promoting sustainable practices on the valuation possibilities.

Keywords: Olive Mill Wastewater, OMWW, FTMIR, data analysis, traceability, classification and discrimination

Article language: En


Publisher: Taras Shevchenko National University, Kiev Ukraine

(Analytical chemistry department at Taras Shevchenko National University, 64 Vladimirskaya STR., Kiev, 01601 UKRAINE)
analysis@univ.kiev.ua, www.univ.kiev.ua, +380 (44) 2393444

The journal is indexed in SCOPUS and Web of Science

The journal website: www.moca.net.ua

The articles in this journal are licensed under CC BY 4.0