Analytical chemistry council

METHODS AND OBJECTS OF CHEMICAL ANALYSIS

ISSN title: "Metody i obʺekty himičeskogo analiza"

An international journal devoted to all aspects of Analytical chemistry

ISSN 2413-6166 (Online), ISSN 1991-0290 (Print)

Kiev University
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A.N. CHEBOTAREV, I.S. EFIMOVA

COMPLEXATION IN MANGANESE(VII)—4-SULFO-2(4`-SULFONAPHTHALENE-1`-AZO)NAPHTHOL-1 REDOX-SYSTEM.

The peculiarities of complexation in manga,nese(VII)—4-sulfo-2(4`-sulfonaphthalene-1`-azo)naphthol-1 redox system in aqueous solution at various pH values have been studied. The formation of manganese (II) at pH=2 and manganese (IV) at pH=6 has been proved in this redox system. We propose two analytical forms with light absorption peaks at 370 and 430 nm, respectively, characterized by manganese microquantities various minimal detection limits.

Keywords: manganese, karmoazine, complexation, analytical forms.


Publisher:Taras Shevchenko National University, Kiev Ukraine

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