Analytical chemistry council

METHODS AND OBJECTS OF CHEMICAL ANALYSIS

ISSN title: "Metody i obʺekty himičeskogo analiza"

An international journal devoted to all aspects of Analytical chemistry

ISSN 2413-6166 (Online), ISSN 1991-0290 (Print)

Kiev University
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Spectrophotometric determination of Cr(III) with Chrome azurol S in the presence of Cr(VI)

Yatskiv O. S., Patsay I. O.

It has been established that interfering influence of Chromium(VI) on spectrophotometric determination of Chromium(III) consists in interaction of Cr(VI) with Chrome azurol S giving Chromium(III). The optimum conditions have been found and the method of Cr(III) selective determination in solutions that contain Cr(VI) has been developed. The determination limit is 7·10,7 mol/l. Up to the 100,multiple amounts of Cr(V²) do not interfere.

Keywords: spectrophotometry, Chromium(III), Chrome azurol S, Chromium(VI), selectivity


Publisher:Taras Shevchenko National University, Kiev Ukraine

(Analytical chemistry department at Taras Shevchenko National University, 64 Vladimirskaya STR., Kiev, 01601 UKRAINE)
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