Analytical chemistry council

METHODS AND OBJECTS OF CHEMICAL ANALYSIS

ISSN title: "Metody i obʺekty himičeskogo analiza"

An international journal devoted to all aspects of Analytical chemistry

ISSN 2413-6166 (Online), ISSN 1991-0290 (Print)

Kiev University
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Determination of chromate traces in water by chemiluminescence

Zui O.V.

 Procedure of indirect chromate determination in waters has been developed based on iodide oxidation by dichromate, gas extraction of iodine formed and chemiluminescence detection of luminol in carrier gas flow. Preliminary coprecipitation of barium chromate with barium carbonate was used for separation from interfering components.The limit of detection for chromate is 7 μg/L. Duration of analysis is 20 min. Procedure was applied for analysis of tap water and sewage water of electroplating industry.

Keywords: chemiluminescence, reactive gas extraction, chromate


Publisher:Taras Shevchenko National University, Kiev Ukraine

(Analytical chemistry department at Taras Shevchenko National University, 64 Vladimirskaya STR., Kiev, 01601 UKRAINE)
analysis@univ.kiev.ua, www.univ.kiev.ua, +380-44-2393266

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