Analytical chemistry council

METHODS AND OBJECTS OF CHEMICAL ANALYSIS

(Metody i Ob''ekty Himicheskogo Analiza)

An international journal devoted to all aspects of Analytical chemistry

ISSN 2413-6166 (Online), ISSN 1991-0290 (Print)

Kiev University
 

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Determination of the Content of Hf in Zirconium Alloys with using a Wide Band X-Ray Emission Filter

O.P. Omelnyk, V.V. Levenets*, A.Yu. Lonin, I.V. Shevchenko, A.O. Shchur

* Corresponding author

National Science Center “Kharkov Institute of Physics and Technology” NAS of Ukraine, 1, Akademichaskaya St., Kharkov, Ukraine, 61108;
*e-mail: levenets@kipt.kharkov.ua

Methods Objects Chem. Anal., 2018, 13(4), p. 153-159

https://doi.org/10.17721/moca.2018.153-159

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Abstract

The possibilities of a non-destructive method of determination of the content of hafnium in zirconium alloys are studied. The method is based on excitation of the characteristic X-ray emission of the atoms of the object of interest, including the L-series of atom of Hf, by external beam of protons accelerated up to 2 MeV. The excited emission is modified by a wide band X-ray emission filter, which is made from pyrolytic graphite plates and measured by a Si-PIN detector. Optimal conditions for measurement of analytical signal were determined after experimental studying. It was shown that under the selected experimental conditions and the measurement time of 10 minutes, the detection limit of Hf in the zirconium matrix is equal 20 ppm. The ways for improving of the metrological characteristics of the technique in the presence of interfering elements are proposed. The content of hafnium and uniformity of its distribution in the cladding of nuclear fuel rod made from the alloy Zr1% Nb was determined.

Keywords:hafnium, zirconium, characteristic X-ray emission, wave dispersion, energy dispersion

Article language: Rus


Publisher:Taras Shevchenko National University, Kiev Ukraine

(Analytical chemistry department at Taras Shevchenko National University, 64 Vladimirskaya STR., Kiev, 01601 UKRAINE)
analysis@univ.kiev.ua, www.achem.univ.kiev.ua, +380-44-2393345

Papers published in Methods and Objects of Chemical Analysis are considered as publications suitable for PhD thesis

The journal website: www.moca.net.ua