Analytical chemistry council

METHODS AND OBJECTS OF CHEMICAL ANALYSIS

ISSN title: "Metody i obʺekty himičeskogo analiza"

An international journal devoted to all aspects of Analytical chemistry

ISSN 2413-6166 (Online), ISSN 1991-0290 (Print)

Kiev University
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Analysis of Elemental and Isotopic Composition of Uranium Ore Concentrate Using LA-ICP-MS

D.V. Kutnii*, S.A. Vanzha, V.V. Levenets

* Corresponding author
National Science Center “Kharkov Institute of Physics and Technology” NAS of Ukraine, 1, Akademichaskaya St., Kharkov, Ukraine, 61108
E-mail: d_kutniy@kipt.kharkov.ua

Methods Objects Chem. Anal., 2015, 10(1), p. 5-10

https://doi.org/10.17721/moca.2015.5-10

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Abstract

Uranium concentrate is a product of hydrometallurgical processing of uranium ore in form of mixture of oxides with general chemical formulae U308 which is the basis for the production of nuclear fuel. The work presents the results of study on direct determination of elemental and isotopic composition of uranium ore concentrate using laser ablation inductively coupled plasma mass-spectrometry (LA-ICPMS). It is shown that the obtained data on isotopic composition of 234U, 235U, 236U, 238U is well matched with data of gamma-spectrometric measurements and thermal ionization mass-spectrometry, and ratio of 235U/238U isotope composition is close to the one observed in nature, 0.00725. Concentrations of major impurities in the range of atomic mass units from 10.811 (B) up to 232.038 (Th) were determined. It is demonstrated that the results of elemental analysis of uranium ore concentrate are well matched with literature data for the majority of the analyzed elements.

Keywords: uranium ore concentrate, mass-spectrometry, laser ablation, isotopic composition, elemental
composition

Article language: Rus

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Publisher:Taras Shevchenko National University, Kiev Ukraine

(Analytical chemistry department at Taras Shevchenko National University, 64 Vladimirskaya STR., Kiev, 01601 UKRAINE)
analysis@univ.kiev.ua, www.achem.univ.kiev.ua, +380-44-2393266

The journal is indexed in SCOPUS and Web of Science

The journal website: www.moca.net.ua